标题:
芳醛转化为芳腈的合成研究进展Recent Research Advances on the Conversion of Aromatic Aldehydes into Aromatic Nitriles
作者:
吴靓, 郑土才, 施金芬, 陈盛, 过海斌
关键字:
芳醛, 芳腈, 醛肟, 脱水, 合成Aromatic Aldehyde; Aromatic Nitrile; Aldoxime; Dehydration; Synthesis
期刊名称:
《Journal of Organic Chemistry Research》, Vol.1 No.2, 2013-08-29
摘要:
综述了由芳醛与羟胺经一步法或两步法转化为芳腈的研究进展，重点讨论了催化剂或脱水剂、溶剂等反应条件，以及反应的适用底物。指出一步法是值得重点研究的芳醛转化为芳腈的方法，而芳醛直接氨氧化合成腈则是本反应最具发展潜力的方向。
This review summarizes the recent researches on the conversion of aromatic aldehydes to nitriles via one-step or two-step method with particular emphasis on the reaction conditions such as catalysts or dehydrating agents, solvents, and the application of reaction substrates. One-step method which converts aromatic aldehydes to nitriles should be the focus for future researches, while direct oxyamination of aromatic aldehydes to nitriles represents the most promising methodology for the conversion.