阴离子有机硅乳液的制备
Synthesis of Anionic Silicone Emulsion
摘要:
从阴离子有机硅乳液的合成出发,引入活性单体,采用微乳液聚合方法制备成氨基及活性基团改性半透明有机硅微乳液,研究了温度控制、乳化体系、活化物体系等方面对乳液性能的影响,并进行了应用试验。结果证明,制备的阴离子乳液的手感滑弹性较好,特别适用于T/R、T/C混纺织物的浸轧柔软整理工艺。
Abstract:
An active monomer was lent into synthesis of anionic silicone emulsion. Amino group modified silicone translucent micro-emulsion was prepared by micro-emulsion polymerization. We studied temperature control, system and activator system to enhance the properties of emulsion. The results show that the prepared anionic emulsion provides excellent smoothness and better elasticity, especially suitable for the soft finishing process of T/R and T/C blended fabric.
参考文献
[1]
|
黄文润 (2001) 氨基改性聚有机硅氧烷柔软整理剂. 有机硅材料, 15, 27-39.
|
[2]
|
张墩明, 蒋锡群, 杨昌正 (2003) 有机硅微乳液的研究进展. 有机硅材料, 17, 17-21.
|
[3]
|
黄英, 刘香鸾, 师彤 (1994) 硅氧烷乳液聚合过程中大颗粒形成机理研究. 应用化学, 11, 44-47.
|
[4]
|
祝海霞 (2003) 亲水性氨基改性有机硅微乳液的合成及应用. 染整技术, 25, 34-37.
|
[5]
|
Perwuelz, A., Novais De Olivera, T. and Caze, C. (1999) Study of wetting at the silicone oil/fiber interface. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 147, 317-329.
http://dx.doi.org /10.1016/S0927-7757(98)00712-2
|
[6]
|
章基凯, 主编 (1999) 有机硅材料. 中国物资出版社, 北京, 99-101.
|