钢材热镀锌助镀剂的研究进展
Research Progress of Hot Dip-Galvanizing Fluxing on Steel
DOI: 10.12677/HJCET.2016.63009, PDF, HTML, XML,  被引量 下载: 2,841  浏览: 8,464 
作者: 徐 娟, 李 波, 秘 雪：中南大学化学化工学院，湖南 长沙
关键词: 热浸镀锌；助镀剂；工艺；Hot Dip-Galvanizing； Fluxing； Technology
摘要: 助镀是热浸镀锌工艺中一道重要的处理工序。本文介绍了热浸镀锌助镀剂的作用机理和选用标准，对影响助镀剂助镀效果的几个因素进行分析并给出其合理范围，阐述了传统锌铵助镀剂的作用机理，综述了近年来新型无铵助镀剂的研究现状，并指出了热浸镀锌助镀剂研究中存在的问题及未来的发展方向。
Abstract: The plating is an important process in hot dip galvanizing. The mechanism and the selection criteria of fluxing of hot dip galvanizing are introduced. Several factors which influence the effect of fluxing are analyzed and the reasonable range is given. The action mechanism of the traditional zinc ammo-nium fluxing is expounded. The recent research status of the new type of free-ammonium fluxing is reviewed. The existing research problems and the future development direction of fluxing of hot dip galvanizing are pointed out.
文章引用：徐娟, 李波, 秘雪. 钢材热镀锌助镀剂的研究进展[J]. 化学工程与技术, 2016, 6(3): 71-77. http://dx.doi.org/10.12677/HJCET.2016.63009

参考文献

[1] 谭杰. 无铵助镀条件下热浸镀锌中Al对镀层形成的影响[D]: [硕士学位论文]. 昆明: 昆明理工大学, 2014.
[2] 冯刚, 侯静, 张琳. 钢铁成分及添加元素对热镀锌组织和性能的影响[J]. 热加工工艺, 2011, 40(4): 118-121.
[3] 朱立. 钢材热镀锌[M]. 北京: 化学工业出版社, 2006.
[4] 邵大伟, 贺志荣, 张永宏, 等. 热浸镀锌技术的研究进展[J]. 热加工工艺, 2012, 41(6): 100-103.
[5] 罗龚, 曾建民. 热浸镀锌反应性润湿及镀层形成研究进展[J]. 应用化工, 2014, 43(3): 543-548.
[6] 曹文平. 热浸镀锌无铵助镀过程中表面活性剂的作用研究[D]: [硕士学位论文]. 昆明: 昆明理工大学, 2013.
[7] 苗立闲, 杜安, 李世杰. 钢材热镀锌技术问答[M]. 北京: 化学工业出版社, 2013.
[8] 何应, 贺志荣, 张永宏, 等. 热浸镀锌助镀剂及其助镀工艺的研究进展[J]. 材料保护, 2013(6): 51-54.
[9] 张欣. 热浸镀锌助镀工艺应用探讨[J]. 中国高新技术企业, 2015(22): 60-61.
[10] 孔纲, 卢锦堂, 许乔瑜. 热浸镀锌助镀工艺的研究与应用[J]. 材料保护, 2005, 38(8): 56-58, 72.
[11] James, I. and England, B. (1976) Hot DIP Galvanizing. US Patent No. 3936540.
[12] Wolfgang, M. (1977) Process for the Hot Tinning Hot Galvanizing and Hot Leading of Iron Articles. GB Patent No. 1489188A.
[13] Yamanaka, S. and Yamamoto, M. (2006) Flux Composition for Hot DIP Coating Zn-AI-Mg Alloy and Method for Manufacturing Hot DIP Zn-AI-Mg Alloy Coated Steel Using the Same. JP Patent No. 2006-188724A.
[14] Endo, H. and Yamamoto, M. (2003) Flux and Method for Hot-DIP Plating AI-Zn Alloy. JP Patent No. 2003-113455A.
[15] 王玉强. 热镀锌用植酸盐助镀剂[P]. 中国专利, 101122000A, 2008-02-13.
[16] Memmi, M., Brevaglier, B. and Natali, S. (2001) Productionofa Zine-Aluminum Alloy Coating by Immersioninto Molten Metal Baths. US Patent No. 6284122.
[17] Hans-Wihelm, L. and Kammel. R. (1985) Method for Hot DIP Galvanizing Metallic Workpieces. US Patent No. 4505958.
[18] Wim, J., Van, O. and Prasanna, V. (2001) Fluxing Process for Galvanization of Steel. US Patent No. 6200636.
[19] Yamanaka, S. and Yamamoto, M. (2005) Flux Composition for Hot DIP Zn-AI Based Alloy Plating and Method of Producing Hot DIP Zn-AI Based Alloy Plated Steel Using the Same. JP Patent No. 2005-248294A.
[20] 张启云, 何眀奕, 曹文平, 等. 表面活性剂对热浸镀锌无铵助镀剂盐膜性能的影响[J]. 热加工工艺, 2013, 42(22): 111-113.
[21] Tatsumi, I., Yoshihiko, T. and Koshi, T. and Tetsuya, N. (1994) Flux Suitable for Coating Molten Zine, Moltenalloy of Aluminum and Zine and Molten Aluminum. US Patent No. 5292377.
[22] 罗中保, 何眀奕, 赵晓军, 等. 氟碳无铵助镀热镀锌镀层组织及耐蚀性能[J]. 金属热处理, 2011, 36(5): 75-78.
[23] 周水芳, 何眀奕, 刘福燕, 等. 3种热浸镀锌助镀剂成膜的均匀性[J]. 材料保护, 2013(1): 48-49, 58.
[24] 李斌. 钢制件热镀锌用无白烟助镀剂及其应用的热镀锌工艺[P]. 中国专利, 103834889A, 2014-06-04.