共价有机框架在光催化制备过氧化氢中的研究进展与展望
Progress and Prospects of Covalent Organic Frameworks in Photocatalytic Preparation of Hydrogen Peroxide
DOI: 10.12677/jocr.2024.121006, PDF,   
作者: 孙倩楠, 廖峭波*：上海理工大学材料与化学学院，上海
关键词: 共价有机框架；光催化；过氧化氢；Covalent Organic Frameworks； Photocatalysis； Hydrogen Peroxide
摘要: 共价有机框架(COFs)是一类新兴的功能性材料，它在光催化领域展现出了巨大的应用潜力，尤其在过氧化氢的合成方面显示出独特的优势。近年来，COFs在光催化合成过氧化氢领域的研究取得了显著的进展。本文旨在详细总结不同类型COFs的设计合成、光催化性能以及相关机理，深入探讨提升COFs在光催化制备过氧化氢性能的策略，包括构建电子供体–受体(D-A)结构、金属掺杂构建异质结和官能团修饰等方面。通过对多篇相关文献的系统分析，强调了COFs在提高光催化效率、增强结构稳定性以及灵活设计光活性单元等方面的独特优势。这些独特优势不仅有望提高过氧化氢的合成效率，还为COFs在光催化中的广泛应用奠定了基础。在此基础上，进一步推动COFs在光催化合成过氧化氢领域的研究，为其未来的发展提供了深刻的理解和启示。总体而言，COFs作为光催化领域的有望材料，具有广阔的应用前景，为绿色能源和可持续发展做出了积极贡献。
Abstract: Covalent Organic Frameworks (COFs), as a novel class of functional materials, have shown tremendous potential in the field of photocatalysis, particularly demonstrating unique advantages in the synthesis of hydrogen peroxide. In recent years, significant progress has been made in the research on COFs in the photocatalytic synthesis of hydrogen peroxide. This paper aims to comprehensively summarize the design, synthesis, photocatalytic performance, and relevant mechanisms of different types of COFs. It delves into strategies to enhance the photocatalytic performance of COFs in the preparation of hydrogen peroxide, including the construction of electron donor-acceptor (D-A) structures, the introduction of metal doping to form heterojunctions, and functional group modifications. Through a systematic analysis of multiple relevant literature sources, the paper highlights the unique advantages of COFs in improving photocatalytic efficiency, enhancing structural stability, and flexibly designing photoactive units. These advantages are expected not only to boost the efficiency of hydrogen peroxide synthesis but also to lay the foundation for the widespread application of COFs in photocatalysis. Building upon this foundation, further advancements in research on the photocatalytic synthesis of hydrogen peroxide with COFs are anticipated, providing a profound understanding and inspiration for their future development. Overall, COFs, as promising materials in the field of photocatalysis, hold broad application prospects and contribute positively to green energy and sustainable development.
文章引用：孙倩楠, 廖峭波. 共价有机框架在光催化制备过氧化氢中的研究进展与展望[J]. 有机化学研究, 2024, 12(1): 74-84. https://doi.org/10.12677/jocr.2024.121006

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